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Centre for Surface Chemistry and Catalysis - IAP-V-03

 

 

Publications of the Centre for Surface Chemistry and Catalysis

2002     2003     2004     2005     in press

2002

The siting of Cu(II) in Mordenite: a Theoretical Spectroscopic Study.  
Delabie, A., Pierloot, K., Groothaert, M., Weckhuysen, B.M., and Schoonheydt, R.A.
Phys.Chem.Chem.Phys., 4, 134-145, 2002.

Catalytic Activity of MCM-41-TBD in the Selective Preparation of Carbamates and Unsymmetrical Alkyl Carbonates from Diethyl Carbonate.  
Carloni, S., De Vos, D.E., Jacobs, P.A., Maggi, R., Sartori, G., and Sartorio, R.
J.Catal., 205, 199-204, 2002. 

Heterogeneous Enzyme Mimics Based on Zeolites and Layered Hydroxides.  
De Vos, D.E., Sels, B., and Jacobs, P.A.
Cattech, 6 (1), 14-29, 2002.

Peroxide Reactions with Anion-exchanged Layered Double Hydroxide Catalysts.
De Vos, D.E., Wahlen, J., Sels, B., and Jacobs, P.A.
Synlett, 3, 367-380, 2002.

Adsorption and Pressure Swing Desorption of NOx in Na-Y Zeolite: Experiments and Modelling.
Brilhac, J.-F., Sultana, A., Gilot, P., and Martens, J.A.
Environ.Sci.Technol., 36 (5), 1136-1140, 2002.

Towards Heterogeneous and Green Versions of Os Dihydroxylation Catalysis.
Severeyns, A., De Vos, D.E., and Jacobs, P.A.
Top.Catal., 19(1), 125-131, 2002.

Silicalite-1 Zeogrid: A New Silica Molecular Sieve with Super-and Ultra Micropores.
Kremer, S.P.B., Kirschhock, C., Tielen, M., Collignon, F., Grobet, P.J., Jacobs, P.A., and Martens, J.A.
Adv.Funct.Mater., 12 (4), 286-292, 2002.

Chromophores in Porous Silicas and Minerals: Preparation and Optical Properties.
Schulz-Ekloff, G., Wöhrle, D., van Duffel, B., and Schoonheydt, R.A.
Micropor.Mesopor.Mater., 51, 91-138, 2002.

Reduction of Prostaglandin Unsaturated Ketones to Secondary Allylic Alcohols by Hydrogen Transfer over Mesoporous Supported PtSn Catalysts.
Coman, S., Parvulescu, V.I., De bruyn, M., De Vos, D.E., and Jacobs, P.A.
J.Catal., 206, 218-229, 2002.

Homogeneous cis-dihydroxylation and Epoxidation of Olefins with High H2O2 Efficiency by Mixed Manganese/Activated Carbonyl Catalyst System.
Brinksma, J., Schmieder, L., van Vliet, G., Boaron, R., Hage, R., De Vos, D.E., Alsters, P., and Feringa, L.
Tetrah.Lett., 43 (14), 2619-2622, 2002.

Reactivity Descriptors and Rate Constants for Electrophilic Aromatic Substitution: Acid Zeolite Catalyzed Methylation of Benzene and Toluene.
Vos, A., Nulens, K., De Proft, F., Schoonheydt, R.A., and Geerlings, P.
J.Phys.Chem.B., 106, 2026-2034, 2002.

Impact of Pd-Mordenite Pretreatment on the Heterogeneity of Heck Catalysis.
Dams, M., Drijkoningen, L., De Vos, D.E., and Jacobs, P.A.
Chem.Commun.,  1062-1063, 2002.

Pd Zeolites as Heterogeneous Catalysts in Heck Chemistry.
Dams, M., Drijkoningen, L., Pauwels, B., Van Tendeloo, G., De Vos, D.E., and Jacobs, P.A.
J.Catal., 209, 225-236, 2002.

Observations on Solvent Flux and Solute Rejection Across Solvent Resistant Nanofiltration Membranes.
Gibbins, E., D'Antonio, M., Nair, D., White, L. S., Freitas dos Santos, L.S., Vankelecom, I.F.J., and Livingston, A.G.
Desalination, 147, 307-313, 2002.

New Evidence for Precursor Species in the Formation of MFI Zeolite in the Tetrapropylammonium Hydroxide-Tetraethyl Orthosilicate-Water System.
Kirschhock, C., Kremer, S.P.B., Grobet, P.J., Jacobs, P.A., and Martens, J.A.
J.Phys.Chem.B., 106 (19), 4897-4900, 2002.

Aqueous enantioselective Hydrogenation of Methyl 2-Acetamidoacrylate with PDMS Occluded Rh-MeDuPHOS Catalyst.
Wolfson, A., Janssens, S., Vankelecom, I.F.J., Geresh, S., Gottlieb, M., and Hershkovitz, M.
Chem.Commun., 4, 388-389, 2002.

Development of a heterogeneous cis-dihydroxylation process with hydrogen peroxide as oxidant. Severeyns, A., De Vos, D.E., and Jacobs, P.A.
Green Chemistry,  4 (4), 380-384, 2002.

The Coordination of CuII in Zeolites, Structure and Spectroscopic Properties.
Delabie, A., Pierloot, K., Groothaert, M., Schoonheydt, R.A., and Vanquickenborne, L.
Eur.J.Inorg.Chem.,  515-530, 2002.

Targeting of the Photocytotoxic Compound AlPcS4 to HeLa Cells by Transferrin Conjugated PEG-Liposomes.
Gijsens, A, Derycke, A., Missiaen, L., De Vos, D.E., Huwyler, J., Eberle, A, and de Witte, P.
Int.J.Cancer,101, 78-85, 2002.

Preparation of Zeogrids through Interposed Stapling and Fusion of MFI Zeolite Type Nanoslabs.
Kremer, S. P. B., Kirschhock, C., Tielen, M., Collignon, F., Grobet, P.J., Jacobs, P.A., and Martens, J.A.
Proc. of the 8th International Symposium "Scientific Bases for the Preparation of Heterogeneous Catalysts", Stud.Surf.Sci.Catal.,  Elsevier, 143, 185 - 192, 2002.

Spectroscopic Study on the Irreversible Deactivation of Chromia/Alumina Dehydrogenation Catalysts.
Puurunen, R.L. and Weckhuysen, B.M.
J.Catal., 210, 418-430, 2002.

Polymeric Membranes in Catalysis.
Vankelecom, I.F.J.
Chem.Rev., 102(10), 3779-3810, 2002.

Increased Catalytic Productivity for Nanofiltration-coupled Heck Reactions Using Highly Stable Catalyst Systems.
Nair, D., Scarpello, J. T., Vankelecom, I.F.J., White, L. S., Freitas dos Santos, L. S., Kloetzing, R. J., Welton, T., and Livingston, A. G.
Green Chemistry, 4 (4), 319-324, 2002.

Mass Spectrometric Methods Prove the Use of Beeswax and Ruminant Fat in Late Roman Cooking Pots.
Kimpe, K., Jacobs, P.A., and Waelkens, M.
J.Chromatography A., 968, 151-160, 2002.

Ordering and Optical Properties of Monolayers and Multilayers of Silica Spheres Deposited by TH Langmuir-Blodgett Method.
Szekeres, M., Kamalin, O., Schoonheydt, R.A., Wostijn, K., Clays, K., Persoons, A., and Dekany, I.
J.Mater.Chem., 12, 3268-3274, 2002.

A New Heterogeneous Catalyst for the Oxidative Carbonylation of Phenol to Diphenyl Carbonate.
Linsen, K., Libens, J., and Jacobs, P.A.
Chem.Commun., (22), 2728-2729, 2002.

Smectite-Type Clay Minerals as Nanomaterials.
Schoonheydt, R.A.
Clays and Clay Minerals ,50 (4), 411-420, 2002.

Reply to the Comment on: Identification of Precursor Species in the Formation of MFI Zeolite in the TPAOH-TEOS-H2O System.
Kirschhock, C., Ravishankar, R., Verspeurt, F., Grobet, P.J., Jacobs, P.A., and Martens, J.A.
J.Phys.Chem.B., 106(12), 3333-3334, 2002.

Aerobic Oxidation of Alcohols with Ruthenium Catalysts in Ionic Liquids.
Wolfson, A., Wuyts, S., De Vos, D.E., Vankelecom, I.F.J., and Jacobs, P.A.
Tetrah.Lett., 43(45), 8107-8110, 2002.

Zeolite Effects on Catalytic Transformations of Fine Chemicals.
De Vos, D.E. and Jacobs, P.A. Guisnet, M. and Gilson, J.-P.
Zeolites for Cleaner Technologies. London, Imperial College Press, Catalytic Science Press, Hutchings, G. ed., (13), 261-279. 2002.

Acid Controlled Alkyne Dimerisation Initiated by a Ru-Carbene Precursor.
Melis, K., De Vos, D.E., Jacobs, P.A., and Verpoort, F.
J.Organometallic Chem., 659, 159-164, 2002.

Standard Reaction of the International Zeolite Association for Acidity Characterization: Ethylbenzene Disproportionation over LaNaY.
De Vos, D.E., Ernst, S., Perego, C., O'Connor, C., and Stöcker, M.
Micropor.Mesopor.Mater., 56(2), 185-192, 2002.

Chemoselective Hydrogen Transfer Reduction of Unsaturated Ketones to Allylic Alcohols with Solid Zr and Hf Catalysts.
De bruyn, M., De Vos, D.E., and Jacobs, P.A.
Adv.Synth.Cat., 344(10), 1120-1125, 2002.

Low-Temperature Destruction of Chlorinated Hydrocarbons over Lanthanide Oxide Based Catalysts.
Van der Avert, P. and Weckhuysen, B.M.
Angew.Chem.(Int.Edit.), 41(24), 4730-4732, 2002.

The Process of Mn(II) Incorporation into Aluminophosphate Zeotypes through High-Field ENDOR Spectroscopy and DFT Calculations.
Arieli, D., Delabie, A., Groothaert, M., Pierloot, K., and Goldfarb, D.
J.Phys.Chem.B., 106, 9086-9097, 2002.

Ordered Mesoporous and Microporous Molecular Sieves Functionalized with Transition Metal Complexes as Catalysts for Selective Organic Transformations.
De Vos, D.E., Dams, M., Sels, B., and Jacobs, P.A.
Chem.Rev., 102, 3615-3640, 2002.

 

2003

Practical Heterogeneous Catalysts for Epoxide Production.
De Vos, D.E., Sels, B., and Jacobs, P.A.   
Adv. Synth. Cat., 345, 457-473, 2003

Recycling of Homogeneous Hydrogenation Catalysts by Dialysis Coupled Catalysis.
De Smet, K., Pleysier, A., Vankelecom, I.F.J., and Jacobs, P.A.   
Chem. Eur. J., 9, 334-338, 2003

Co-Immobilisation of Transition Metal Complexes and Ionic Liquids in a Polymeric Support for Liquid Phase Hydrogenations.
Wolfson, A., Vankelecom, I.F.J., and Jacobs, P.A.  
Tetrah. Lett., 44, 1195-1198, 2003

Synthesis of Co-rich CoAPO-5 Molecular Sieves: A Comparison between Glycerol and Water as Solvent.
Fan, W. and Weckhuysen, B.M.   
J. Nanosc. Nanotech, 3, 1-6, 2003

Preferential Siting of Iron Atoms in MFI Type Ferrisilicate Zeolite Framework: An Attempt to Explain Experimental Data with TPA-Silicate Solution Chemistry.
Theunissen, E., Kirschhock, C., Kremer, S.P.B., Habermacher, D., and Martens, J.A.   
Eur. J. Inorg. Chem., 1296-1298, 2003

Development of a Fixed-Bed Continuous-Flow High-Throughput Reactor for Long-Chain n-Alkane Hydroconversion.
Huybrechts, W., Mijoin, J., Jacobs, P.A., and Martens, J.A.   
App. Catal. A-Gen., 243, 1-13, 2003

Identification of Cu(II) Coordination Structures in Cu-ZSM-5, based on a DFT/ ab initio Assignment of the EPR Spectra.
Groothaert, M., Pierloot, K., Delabie, A., and Schoonheydt, R.A.
Phys. Chem. Chem. Phys., 5, 2135-2144, 2003

The Role of the Solvent in the Asymmetric Hydrogenation of β-keto esters with Ru-BINAP.
Wolfson, A., Vankelecom, I.F.J., Geresh, S., and Jacobs, P.A.   
J. Molec. Cat, 198, 39-45, 2003

CrIII(salen) Catalysed Asymmetric Ring Opening of Monocyclic Terpene-Epoxides.
Dioos, B. and Jacobs, P.A.
Tetrah. Lett., 44, 4715-4717, 2003

Activation of Hydrogen Peroxide through Hydrogen-Bonding Interaction with Acidic Alcohols: Epoxidation of Alkenes in Phenol.
Wahlen, J., De Vos, D.E., and Jacobs, P.A.   
Organic Letters, 5, 1777-1780, 2003

MCM-41 Immobilised Borate Co-Catalyst for Metallocene Catalyzed Propene Oligomerization.
Kwanten, M., Carrière, B.A.M., Grobet, P.J., and Jacobs, P.A.   
Chem. Commun., 1508-1509, 2003

Transition Metal anion exchanged Layered Double Hydroxides as a bioinspired model of Vanadium Bromoperoxidase.
Sels, B., De Vos, D.E., Buntinx, M., and Jacobs, P.A.  
 
J. Catal., 216, 288-297, 2003

Toward a Better Control of Internal Structure and External Morphology of Mesoporous Silicas Synthesized Using a Nonionic Surfactant.
Léonard, A., Blin, J.L., Robert, M., Jacobs, P.A., Cheetham, A.K., and Su, B.-L.   
Langmuir, 19, 5484-5490, 2003

Bis (µ-oxo)dicopper in Cu-ZSM-5 and its Role in the Decomposition of NO: a Combined in situ XAFS, UV-vis-NIR and Kinetic Study.
Groothaert, M., van Bokhoven, J., Battiston, A., Weckhuysen, B.M., and Schoonheydt, R.A.   
J. Am. Chem. Soc., 125, 7629-7640, 2003

Bis(µ-oxo)dicopper as Key Intermediate in the Catalytic Decomposition of Nitric Oxide.
Groothaert M., Lievens K., van Bokhoven J., Battiston A., Weckhuysen B.M., Pierloot K., and Schoonheydt, R.A.   
Chem. Phys. Chem., 4, 626-630, 2003

A Zeolite-Enzyme Combination for Biphasic Dynamic Kinetic Resolution of Benzylic Alcohols.
Wuyts, S., De Temmerman, K., De Vos, D.E., and Jacobs, P.A.   
Chem. Commun., 1928-1929, 2003

Comparison of Hexamethylhypericin and Tetrabromohypericin to Hypericin for their in vivo efficacy as PDT Tools.
Delaey, E., Zupkó, I., Chen, B., Derycke, A., van Laar, F., De Vos, D.E., and de Witte, P.   
Int. J. Oncol., 23, 519-524, 2003

Toward Waste-Free Production of Heck Products with a Catalytic Palladium System under Oxygen.
Dams, M., De Vos, D.E., Celen, S., and Jacobs, P.A.   
Angew. Chem. (Int. Edit. ), 42, 3512-3515, 2003

Microgravity Effect on the Self-Organization of Silicalite-1 Nanoslabs.
Kremer, S.P.B., Theunissen, E., Kirschhock, C., Jacobs, P.A., Martens, J.A., and Herfs, W.   
Adv. Space Res., 32, 259-263, 2003

Investigation of the Permeability and Selectivity of  Gases and Volatile Organic Compounds for Polydimethylsiloxane Membranes
De Bo, I., Van Langenhove, H., Pruuost, P., De Neve, J., Pieters, J., Vankelecom, I.F.J., and Dick, E.  
J. Mem. Sci., 215, 303-319, 2003

Catalytic application of a Ru-alkylidene in the nucleophilic addition of several carboxylic acids on terminal alkynes and the homocoupling of 1-alkynes
Melis, K, De Vos, D, Jacobs, P, Verpoort, F.  
J. Organometal. Chem., 671 (1-2): 131-136, 2003

Tiling Silicalite-1 nanoslabs into 3D mosaics
Kremer,  S. P. B., Kirschhock, C., Aerts, A., Villani, K., Martens, J.A., Lebedev, O.I., and Van Tendeloo, G.  
Adv.Mater., 15, 1705-1707, 2003

DFT Study on the Electrophilic Aromatic Substitution Catalyzed by Lewis Acids.
Vos, A., Schoonheydt, R.A., De Proft, F., and Geerlings, P.   
J.Catal., 220, 333-346, 2003   

An Operando Optical Fiber UV-vis Spectroscopic Study of the Catalytic Decomposition of NO and N2O over Cu-ZSM-5.
Groothaert, M., Lievens, K., Weckhuysen, B.M., and Schoonheydt, R.A.   
J.Catal., 220, 500-512, 2003 

Combinatorial Screening to Conventional Testing of Antimony Rich Selective Oxidation Catalysts.
Paul, J., Urschey, J., Jacobs, P.A., Maier, W. F., and Verpoort, F.     
J.Catal., 220, 136-145, 2003   

CrIII(salen) impregnated on Silica for Asymmetric Ring Opening Reactions and its Recovery via Desorption/Re-Impregnation.
Dioos, B. and Jacobs, P.A.   
Tetrah.Lett., 44, 8815-8817, 2003

Ultra-thin Zeolite Films Prepared by Spin-Coating Silicalite-1 Precursor Solutions
Doyle,A.M., Rupprechter,G., Kirschhock,C. Martens,J.A., Freund,H.-J.    Chem.Phys.Lett., 382, 404-409, 2003 

 Mesoporous Zr and Hf catalysts for Chemoselective MPV Reductions of Unsaturated Ketones
De bruyn, M., Limbourg, M., Denayer, J.F., Baron, G.V., Parvulescu, V.I., Grobet, P.J., De Vos, D.E., Jacobs, P.A.
App. Catal. A-Gen, 254, 189-201, 2003

Chemistry of Silica at Different Cocentrations of non-Ionic Surfactant Solutions: Effect of pH of the Synthesis gel on the Preparation of Mesoporous Silicas
Léonard, A., Blin, J.L., Jacobs, P.A., Grange, P., Su, B.-L.
Micropor. Mesopor. Mater., 6, 59-73, 2003

Surfacial, Liquid Sorption and Monolayer-Forming Properties of Hydrophilic and Hydrophobic Stober Silica Particles
Dekany, I., Szekeres, M., Schoonheydt, R.A.
Colloid and Polymer Science, 282, 1-6, 2003

Reactivity Descriptors and Rate Constants for Acid Zeolite Catalyzed Ethylation and Isopropylation of Benzene.
Vos, A., Schoonheydt, R.A., De Proft, F., and Geerlings, P.
J.Phys.Chem.B, 107 (9), 2001-2008, 2003  

Chemoselective Reduction of Complex α, β-unsaturated Ketones to Allylic Alcohols over Ir Metal Particles on Beta Zeolites
De bruyn, M., Coman, S., Bota, R., Parvulescu, V.I., De Vos, D.E., Jacobs, P.A.
Angew.
Chem. (Int. Edit.), 42, 5333-5336, 2003

Solid Materials as Sources for Synthetically Useful Singlet Oxygen
Wahlen, J., De Vos, D.E., Jacobs, P.A., Alsters, P.
Adv. Synth. Cat., 346, 152-164, 2003

Molecular and Particulate Organization in Dye-Clay Films Prepared by the Langmuir-Blodgett Method.
Ras R., van Duffel B., and Schoonheydt R.A.   
“2001: a Clay Odyssey” Proceedings of the 12th International Clay Conference, July 22-28, 2001 Bahia Blanca, Argentina, Dominguez,E., Mas,G.R., Cravero,F., eds., Elsevier, chpt. 4, 473-480, 2003

Preparation of nanofiltration membranes.
Vankelecom, I.F.J., De Smet, K., Gevers, L., and Jacobs, P.A.   
Nanofiltration - Principles and Applications, 4, 1-29, 2003 

 

2004

Esterification and Transesterification of Renewable Chemicals.
Hoydonckx, H., De Vos, D.E., Chavan, S., and Jacobs, P.A.
Top. Catal., 27, 81-94, 2004

Solid Materials as Sources for Synthetically Useful Singlet Oxygen
Wahlen, J., De Vos, D.E., Jacobs, P.A., Alster, P.L.
Adv.Synth.Catal. 346, 152-164, 2004 

Adsorptive Separation of NOx in Presence of SOx from Gas Mixtures Simulating Lean Burn Engine Exhaust by Pressure Swing Process on Na-Y Zeolite.
Sultana, A., Habermacher, D., Kirschhock, C., and Martens, J.A.
Appl. Catal. B-Environ., 48, 65-76, 2004

Physico-Chemical Interpretation of the SRNF Transport Mechanism for Solvents through Dense Silicone Membranes.
Vankelecom, I.F.J., De Smet, K., Gevers, L., Livingston, A.G., Nair, D., Aerts, S., Kuypers, S., and Jacobs, P.A.
J. Mem. Sci., 231, 99-108, 2004

Titanium Silicalite 1 (TS-1) Catalyzed  Oxidative Transformations of Furan Derivatives with Hydrogen Peroxide.
Wahlen, J., Moens, B., De Vos, D.E., Alsters, P., and Jacobs, P.A.
Adv. Synth. Cat., 346, 333-338, 2004

Reaction Mechanisms of Lean-Burn Hydrocarbon SCR over Zeolite Catalysts.
Brosius, R. and Martens, J.A.
Top. Catal., 28, 119-130, 2004

Mechanism of the Catalytic Oxidation of Hydrocarbons by N-hydroxyphthalimide: a Theoretical Study.
Hermans, I., Vereecken, L., Jacobs, P.A., and Peeters, J.
Chem. Commun., 1140-1141, 2004

Low-Temperature Destruction of Carbon Tetrachloride over Lanthanide Oxide-Based Catalysts: from Destructive Adsorption to a Catalytic Reaction Cycle.
Van der Avert, P., Podkolzin, S., Manoilova, O., De Winne, H., and Weckhuysen, B.M.
Chem. Eur. J., 10, 1637-1646, 2004

Combinatorial Discovery of New Catalysts for the Selective Oxidation of Isobutane.
Paul, J., Jacobs, P.A., Weiss, A., and Maier, W.F.
App. Catal. A-Gen., 265, 185-193, 2004

Non-Equilibrium Processes of Interchain Association Induced by Cs+ Ions in -Carrageenan Aqueous Solutions.
Reynaert, H.R., Cuppo, F., Kremer, S.P.B., and Martens, J.A.
Int. J. Biol. Macromol., 34, 43-47, 2004

Novel MoVSbOx-Type Catalysts for Selective Isobutane Oxidation.
Paul, J., Groothaert, M., Kirschhock, C., Lebedev, O.I., Jacobs, P.A., and Maier, W.F.
Catal. Today, 91-92, 265-269, 2004

Adsorption Chemistry of Sulphur Dioxide in Hydrated Na-Y Zeolite.
Kirschhock, C., Sultana, A., Godard, E., and Martens, J.A.
Angew. Chem. (Int. Edit. ), 43, 3722-3724, 2004

Palladium catalysed C-C coupling reactions under oxygen.
Dams, M., De Vos, D.E., and Jacobs, P.A.
Speciality Chemicals Magazine, June 2004, 42-44, 2004

Recycling of the Homogeneous Co-Jacobsen Catalyst through Solvent-Resistent Nanofiltration (SRNF).
Aerts, S., Weyten, H., Buekenhoudt, A., Gevers, L., Vankelecom, I.F.J., and Jacobs, P.A.
Chem. Commun., 710-711, 2004

Perturbation and Tracer Chromatography Study of Hydrocarbon Adsorption from Simulated Exhaust Gas on Fe-MFI and MOR Type Zeolite Catalysts.
Boulard, S., Gilot, P., Habermacher, D., Brosius, R., and Martens, J.A.
Top. Catal., 30, 49-53, 2004

Tropopause Chemistry Revisited: HO2-initiated Oxidation as a Major Acetone Sink.
Hermans, I., Nguyen, T.L., Jacobs, P.A., and Peeters, J.
J. Am. Chem. Soc., 126, 9908-9909, 2004

Hybrid Langmuir Blodgett Monolayers Containing Clay Minerals: Effect of Clay Concentration and Layer Charge Density on the Film Formation.
Ras, R., Nemeth, J., Johnston, C.T., DiMasi, E., Dekany, I., and Schoonheydt, R.A.
Phys. Chem. Chem. Phys., 6, 4174-4184, 2004

Reply to the comment "On the TEM and AFM Evidence of Zeosil Nanoslabs Present during the Synthesis of Silicalite-1".
Kirschhock, C., Liang, D., Aerts, A., Aerts, C., Kremer, S.P.B., Jacobs, P.A., Van Tendeloo, G., and Martens, J.A.
Angew. Chem. (Int. Edit. ), 116, 2-4, 2004

NO Oxidation Kinetics on Iron Zeolites: Influence of Framework Type and Iron Speciation.
Brosius, R., Habermacher, D., Martens, J.A., Vradman, L., Hershkovitz, M., Capek, L., Sobalik, Z., Dedecek, J., Wichterlova, B., Tokarova, V., and Gonsiorova, O.
Top. Catal., 30/31, 333-339, 2004

Infrared reflection absorption (IRRAS) study of smectite clay monolayers.
Ras, R., Nemeth, J., Johnston, C.T., Dekany, I., and Schoonheydt, R.A.
Thin Solid Films, 466, 291-294, 2004

Coordination of CrIII(salen) on Functionalised Silica for Asymmetric Ring Opening Reactions of Epoxides.
Dioos, B., Geurts, W., and Jacobs, P.A.
Catal. Lett., 97, 125-129, 2004

Aluminium Incorporation into MCM-48 toward the Creation of Bronsted Acidity.
Collart, O., Cool, P., Van der Voort, P., Meynen, V., Vansant, E.F., Houthoofd, K., Grobet, P.J., Lebedev, O.I., and Van Tendeloo, G.
J. Phys. Chem. B., 108, 13905-13912, 2004

A Simple, Efficient Alternative for Highly Stereoselective Iodoacetoxylation of Protected Glycals.
Gammon, D., Kinfe, H.H., De Vos, D.E., Jacobs, P.A., and Sels, B.
Tetrah. Lett., 45, 9533-9536, 2004

Acid zeolites as alcohol racemization catalysts: Screening and application in a biphasic dynamic kinetic resolution.
Wuyts, S., De Temmerman, K., De Vos, D.E., and Jacobs, P.A.
Chem. Eur. J., 11, 386-397, 2004

Transferrin-conjugated Liposome Targeting of Photosensitizer AlPcS4 to Rat Bladder Carcinoma Cells
Derycke, A.S.L., Kamuhabwa, A., Gijssens, A., Roskams, T., De Vos, D.E., Kasran, A., Huwyler, J., Missiaen, L., De Witte, P.A.M.
J. Nat.
Cancer Institute 96(21): 1620-1630, 2004

Epoxide Yield Determination of Oils and Fatty Acid Methyl Esters Using 1H NMR.
Aerts, H. and Jacobs, P. A.
J.Am.Oil Chem.Soc., 81 (9), 841-846, 2004

Assessing the Relationship between Form and Use of Different Kinds of Pottery from the Archaeological Site Sagalassos (Southwest Turkey) with Lipid Analysis.
Kimpe, K., Drybooms, C., Jacobs, P.A., Degeest, R., and Waelkens, M.
 J. Arch. Sc., 31, 1503-1510, 2004

Orientation and Conformation of Octadecyl Rhodamine B in Hybrid Langmuir-Blodgett Monolayers Containing Clay Minerals.
Ras, R., Nemeth, J., Johnston, C.T., Dékany, I., and Schoonheydt, R.A.
Phys. Chem. Chem. Phys., 6, 5347-5352, 2004

Swelling Clays (Smectites) and Nanofilms
Schoonheydt, R.A.
 "Encyclopedia of Supramolecular Chemistry", 2004

Zeolite Effects in the Sustainable and Green Synthesis of Intermediates and Fine Chemicals.
Jacobs, P.A. and De Vos, D.E.

Proceedings of the 14th International Zeolite Conference, Stud.Surf.Sci.Catal, 153, 16pp., 2004

 

2005

REPRINTS

 

Bromide-assisted Oxidation of Substituted Phenols with Hydrogen Peroxide to the Corresponding p-Quinol abd p-Quinol Ethers over WO42- exchanged Layered Double Hydroxides.
Sels B., De Vos D.E., and Jacobs P.A.
Angew. Chem. (Int. Edit. ), 44, 310-313, 2005

Acid zeolites as alcohol racemization catalysts: Screening and application in a biphasic dynamic kinetic resolution.
Wuyts S., De Temmerman K., De Vos D.E., and Jacobs P.A.
Chem. Eur. J., 11, 386-397, 2005

A New Catalytic Route for the Oxidative Halogenation of Cyclic Enol Ethers Using Tungstate Exchanged on Takovite.
Sels B., Levecque P., Brosius R., De Vos D.E., Jacobs P.A., Gammon D., and Kinfe H.H.
Adv. Synth. Cat., 347, 93-104, 2005

NO+: Infrared Probe for basic zeolites.
Thibault-Starzyk F., Marie O., Malicki N., Vos A., Schoonheydt R.A., Geerlings P., Henriques C., Pommier C., and Massiani P.
Chem. Commun., 2005

Rotational Entropy Driven Alkane/Isoalkane Separation.
Denayer J.F., Ocakoglu R., Arik I.C., Kirschhock C., Martens J.A., and Baron G.V.
Angew. Chem. (Int. Edit. ), 44, 400-403, 2005

The Influence of Solvent Choice, Acid Activation and Surfactant Addition on the Hydrolytic Kinetic Resolution (HKR) of Terminal Epoxides.
Aerts S., Bullen J., Weyten H., Vankelecom I.F.J., and Jacobs P.A.
Tetrahedron Asymmetr., 16, 657-660, 2005

Benzimidazole-functionalized Dendrons as Molybdenum Supports for Selective Epoxidation Catalysis.
Chavan S., Maes W., Wahlen J., Jacobs P.A., De Vos D.E., and Dehaen W.
Catalysis Communications, 6, 241-246, 2005

Impregnation of Dimeric CrIII (Salen) on Silica and its Application in Epoxide Asymmetric Ring Opening Reactions.
Dioos B. and Jacobs P.A.
App. Catal. A-Gen., 282, 181-188, 2005

High Throughput Screening for Rapid Development of Membranes and Membrane Processes.
Vandezande P., Gevers L., Paul J., Vankelecom I.F.J., and Jacobs P.A.
J. Mem. Sci., 250, 305-310, 2005

Gold redox catalysis for selective oxidation of methane to methanol.
De Vos D.E. and Sels B.
Angew. Chem. (Int. Edit. ), 117, 30-32, 2005

Lanthanum-Exchanged Zeolites as Active and Selective Catalysts for the Generation of Singlet Oxygen from Hydrogen Peroxide.
Wahlen J., De Vos D.E., De Hertogh S., Jacobs P.A., Nardello V., Aubry J.-M., and Alsters P.
Chem. Commun., 7, 927-929, 2005

Beneficial Effect of Water as Second Solvent in Ionic Liquid Biphasic Catalytic Hydrogenations.
Wolfson A., Vankelecom I.F.J., and Jacobs P.A.
Tetrah. Lett., 46, 2513-2516, 2005

Selective Oxidation of Methane into Methanol by the Bis(m-oxo) Dicopper Core Stabilised on ZSM-5 and Mordenite Zeolites.
Groothaert M., Smeets P., Sels B., Jacobs P.A., and Schoonheydt R.A.
J. Am. Chem. Soc., 127, 1394-1395, 2005

NO2 Disproportionation for the IR Characterisation of Basic Zeolites.
Marie O., Malicki N., Pommier C., Massiani P., Vos A., Schoonheydt R.A., Geerlings P., Henriques C., and Thibault-Starzyk F.
Chem. Commun., 8, 1049-1051, 2005

Kinetics of a-Hydroxy-Alkylperoxil Radicals in Oxidation Processes. HO2-initiated Oxidation of Ketones.
Hermans
I., Müller J.F., Nguyen T.L., Jacobs P.A., and Peeters J.
 J. Phys. Chem. A, 2005

Optimization of MoVSb Oxide Catalyst for Partial Oxidation of Isobutane by Combinatorial Approaches.
Paul J., Janssens R., Denayer J.F., Baron G.V., and Jacobs P.A.
Journal of Combinatorial Chemistry, 2005

Free Volume and Interstitial Cavities in Silica Filled Poly (1-Trimethylsilyl-1-Propyne) Nanocomposites.
Winberg P.M., De Sitter K., Vankelecom I.F.J., and Maurer F.H.J.
Macromolecules, 38, 3776-3782, 2005

Autoxidation of Cyclohexane: conventional views challenged by theory and experiment.
Hermans
I., Nguyen T.L., Jacobs P.A., and Peeters J.
Chem. Phys. Chem., 6, 637-645, 2005

Analysis of Fe species in zeolites by UV-Vis-NIR, IR spectra and voltammetry. Effect of preparation, Fe loading and zeolite type.
Capek L., Dedecek J., Grygar P., Wichterlova B., Sobalik Z., Martens J.A., Brosius R., and Tokarova V.
Micropor. Mesopor. Mater., 80, 279-289, 2005

Synthesis and Characterization of Zeogrid Molecular Sieves.
Kremer S.P.B., Kirschhock C., Jacobs P.A., and Martens J.A.
C. R. Chimie, 8, 379-390, 2005

Zeolite Filled Polydimethylsiloxane (PDMS) as an Improved Membrane for Solvent-Resistant Nanofiltration (SRNF).
Gevers L., Vankelecom I.F.J., and Jacobs P.A.
Chem. Commun., 2500-2502, 2005

Chemical Synthesis of (S)-4,5-Dihydroxy-2,3-pentanedione, Bacterial Signal Molecule Precursor, and Validation of its Activity in Salmonella Typhimurium.
De Keersmaecker S., Varszegi C., van Boxel N., Habel L., Metzger K., Daniels R., Marchal K., De Vos D.E., and Vanderleyden J.
J. Biol. Chem., 280, 19563-19568, 2005

The role of additional solvents in transition metal complex catalyzed asymmetric reductions in ionic liquid containing systems.
Wolfson A., Vankelecom I.F.J., and Jacobs P.A.
J. Organometallic Chem., 690, 3558-3566, 2005

Zeolite Effects in Liquid Phase Organic Transformations.
De Vos D.E. and Jacobs P.A.
Micropor. Mesopor. Mater., 82, 293-304, 2005

Design and Synthesis of Hierarchical Materials from Ordered Zeolitic Building Units.
Martens J.A., Kirschhock C., Kremer S.P.B., Vermant J., Van Tendeloo G., and Jacobs P.A.
Chem. Eur. J., 11, 4306-4313, 2005

Zeotile-2: a Microporous Analogue of MCM-48.
Kremer S.P.B., Kirschhock C., Aerts A., Aerts C., Houthoofd K., Grobet P.J., Jacobs P.A., Lebedev O.I., Van Tendeloo G., and Martens J.A.
Solid State Sciences, 7, 861-867, 2005

Unexpected Microgravity Effect during the Self-Organization of Silicalite-1 Nanoslabs.
Kirschhock C., Kremer S.P.B., Theunissen E., Jacobs P.A., Vermant J., Pauwels B., Lebedev O.I., Van Tendeloo G., and Martens J.A.
Microgravity Science and Technology, 74-78, 2005

Tailored Catalytic Propene Trimerization over Acid Zeolites with Tubular Pores.
Martens J.A., Verrelst W.H., Mathys G., Brown S., and Jacobs P.A.
Angew. Chem. (Int. Edit. ), 117, 5833-5836, 2005

Disproportionation of Hydrogen Peroxide into Singlet Oxygen Catalyzed by Lanthanum-Exchanged Zeolites.
Wahlen J., De Hertogh S., De Vos D.E., Nardello V., Bogaert S., Aubry J., Alsters P., and Jacobs P.A.
J. Catal., 233, 422-433, 2005

Acid-Metal Balance of a Hydrocracking Catalyst: Ideal Versus Nonideal Behavior.
Thybaut J., Narasimhan C.S.L., Denayer J.F., Baron G.V., Jacobs P.A., Martens J.A., and Marin G.B.
Ind. Eng. Chem. Res., 44, 5159-5169, 2005

Operando FTIR Study of Reaction Pathways of Selective Catalytic Reduction of  NOx with Decane in the Presence of Water on Iron-Exchanged MFI-Type Zeolite.
 Brosius R., Bazin P., Thibault-Starzyk F., and Martens J.A.
J. Catal., 234, 191-198, 2005

Chemical Instability of Octadecylammonium Monolayers.
Ras R., Johnston C.T., and Schoonheydt R.A.
Chem. Commun., 4095-4097, 2005

Catalytic Oxidation of 1,2-diols to a-hydroxycarboxylates with Stabilized Gold Nanocolloids Combined with a Membrane-Based Catalyst Separtion.
Mertens P., Bulut M., Gevers L., Vankelecom I.F.J., Jacobs P.A., and De Vos D.E.
Catal. Lett., 102, 57-61, 2005

Molybdate-Exchanged Layered Double Hydroxides for the Catalytic Disproportionation of Hydrogen Peroxide into Singlet Oxygen: Evaluation and Improvements of 1O2 Generation by Combined Chemiluninescence and Trapping Experiments.
Wahlen J., De Vos D.E., Sels B., Nardello V., Aubry J., Alsters P., and Jacobs P.A.
App. Catal. A-Gen., 293, 120-128, 2005

 

in press

Synergetic Effects in intimate Mixtures of PT/ZSM-48 and PT/ZSM-22 Zeolites in Bifunctional Catalytic Chain Branching of n-alkanes.
Hastoy, G., Guillon, E., and Martens, J. A.
Stud.Surf.Sci.Catal.

 Characterization of COK-5, Member of a New Family of Zeolites with Multiple Channel Systems.
Kirschhock, C., Bons, A. J., Mertens, M., Ravishankar, R., Mortier, W. J., Jacobs, P. A., and Martens, J. A.
chem.Mat.

 Effect of Solute Geometry and Orientation on the Rejection of Uncharged Compounds by Nanofiltration.
Santos, J. L. C., de Beukelaar, P., Vankelecom, I. F. J., Velizarov, S., and Crespo, J. G.
J.Mem.Sci.

 The Use of 1H NMR for Yield Determination in the Regioselective Epoxidation of Squalene.
Aerts, H., Sels, B., and Jacobs, P. A.  
J.Am.Oil Chem.Soc.

 In situ Space and Time Resolved Sorption Kinetics of Anionic Dyes on Individual LDH Crystals.
De Vos, D. E., Roeffaers, M., Sels, B., Jacobs, P. A., Loos, D., Müllen, K., and Hofkens, J.
Chem.Phys.Chem.

 Kinetic Experiments and Modelling of Complex deNOx System: Decane SCR of NOx in Gas Phase and over Iron MFI Type Zeolite Catalyst.
Vradman, L., Hershkovitz, M., Capek, L., Wichterlova, B., Brosius, R., and Martens, J. A.
Ind.Eng.Chem.Res.

 Physico-chemical Interpretation of the SRNF Transport Mechanism for Solutes through Dense Silicone Membranes.
Gevers, L., Meyen, G., De Smet, K., Van De Velde, P., Du Prez, F., Vankelecom, I. F. J., and Jacobs, P. A.
J.Mem.Sci.

 Cu Based Zeolites: a UV-vis Study of the Active Site in the Selective Methane Oxidation at Low Temperatures.
Smeets, P., Groothaert, M., and Schoonheydt, R. A.
Catal.Today

 

 

     
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