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Center for Surface Chemistry and Catalysis - Research in pictures

 

Tearing structures

Tearing structures

Zeolites are made from linked SiO4 tetrahedra and contain channels and cavities. Many zeolites are built from similar buiding units. a famous example is zeolite A (LTA) and faujasite (FAU) which are both constructed from sodalite-cages (sod).
Sometimes different structures have very similar connectivities of identical units and can form material families with high degree of disorder. The ZSM-48 family is an example.
A detailed analysis of 2 samples of this family revealed that shear forces during synthesis can transform one structure into the other.
This study was done in collaboration with EMAT in Antwerp and IFP in Lyon

The studied samples consisted of needles bunched together. The detailed Transmission Electron Microscopy (TEM) study revealed that during synthesis at first one type of structure is formed. The needles then stack. If shear is caused by the bunching, part of the initial structure can tear as shown in the video. The result is the presence of two different crystal structures next to each other.

"Ordered End-Member of ZSM-48 Zeolite Family"
with as authors
C. E. A. Kirschhock, D. Liang, G. Van Tendeloo, A. Fécant, G. Hastoye, G. Vanbutsele, N. Bats, E. Guillon and J. A. Martens
has been accepted for publication by Chemistry of Materials

 

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